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11.
Dr. Shu Min Tan Dr. Carmen C. Mayorga-Martinez Prof. Zdeněk Sofer Prof. Martin Pumera 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(29):6479-6483
Efficient exfoliation and downsizing of Sb2S3 and Bi2S3 layered compounds by using scalable bipolar electrochemistry on their suspensions in aqueous media are here demonstrated. The resulting samples were characterized in detail by transmission electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy; their electrochemistry toward hydrogen evolution was also investigated. Hydrogen evolution ability of exfoliated Sb2S3 and Bi2S3 was investigated and compared to the bulk counterparts. 相似文献
12.
Nobutaka Yoshimura Dr. Atsushi Kobayashi Dr. Masaki Yoshida Prof. Masako Kato 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(70):16939-16946
To investigate the effect of the surface structure of dye-sensitized photocatalyst nanoparticles, we prepared three types of RuII-photosensitizer (PS)-double-layered Pt-cocatalyst-loaded TiO2 nanoparticles with different surface structures, Zr- RuCP6 -Zr- RuP6 @N wt %Pt-TiO2, RuCP6 -Zr- RuP6 @N wt %Pt-TiO2, and RuCP2 -Zr- RuP6 @N wt %Pt-TiO2 (N=0.2, 1, and 5), and evaluated their photocatalytic H2 evolution activity in the presence of redox-reversible iodide as the electron donor. Although the driving force of the electron injection from I− to the photo-oxidized RuIII PS is comparable, the activity increased in the following order: RuCP2 -Zr- RuP6 @1 wt %Pt-TiO2 < RuCP6 -Zr- RuP6 @1 wt %Pt-TiO2 < Zr- RuCP6 -Zr- RuP6 @1 wt %Pt-TiO2. The apparent quantum yield of Zr- RuCP6 -Zr- RuP6 @1 wt %Pt-TiO2 in the first hour reached 1 %. Zeta-potential measurements suggest that the surface Zr4+-phosphate groups attracted I− anions to the nanoparticle–solution interface. Our results indicate that the surface modification of dye-sensitized photocatalysts is a promising approach to enhance photocatalytic activity with various redox mediators. 相似文献
13.
In this work, we designed and studied a feasible dual-layer binary metagrating, which can realize controllable asymmetric transmission and beam splitting with nearly perfect performance. Owing to ingenious geometry configuration, only one meta-atom is required to design for the metagrating system. By simply controlling air gap between dual-layer metagratings, high-efficiency beam splitting can be well switched from asymmetric transmission to symmetric transmission. The working principle lies on gap-induced diffraction channel transition for incident waves from opposite directions. The asymmetric/symmetric transmission can work in a certain frequency band and a wide incident range. Compared with previous methods using acoustic metasurfaces, our approach has the advantages of simple design and tunable property and shows promise for applications in wavefront manipulation, noise control and one-way propagation. 相似文献
14.
Tingke Rao Prof. Maria Luisa Saladino Prof. Yuanxing Fang Prof. Xinchen Wang Dr. Cristina Giordano 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(72):16676-16682
A versatile synthetic strategy for the preparation of multimetallic oxynitrides has been designed and here exemplarily discussed considering the preparation of nanoscaled zinc–gallium oxynitrides and zinc–gallium–indium oxynitrides, two important photocatalysts of new generation, which proved to be active in key energy related processes from pollutant decomposition to overall water splitting. The synthesis presented here allows the preparation of small nanoparticles (less than 20 nm in average diameter), well-defined in size and shape, yet highly crystalline and with the highest surface area reported so far (up to 80 m2 g−1). X-ray diffraction studies show that the final material is not a mixture of single oxides but a distinctive compound. The photocatalytic properties of the oxynitrides have been tested towards the decomposition of an organic dye (as a model reaction for the decomposition of air pollutants), showing better photocatalytic performances than the corresponding pure phases (reaction constant 0.22 h−1), whereas almost no reaction was observed in absence of catalyst or in the dark. The photocatalysts have been also tested for H2 evolution (semi-reaction of the water splitting process) with results comparable to the best literature values but leaving room for further improvement. 相似文献
15.
Dr. You Xu Xingjie Chai Tianlun Ren Hongjie Yu Shuli Yin Dr. Ziqiang Wang Prof. Dr. Xiaonian Li Prof. Dr. Liang Wang Dr. Hongjing Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(70):16074-16080
The realization of water electrolysis on the basis of highly active, cost-effective electrocatalysts is significant yet challenging for achieving sustainable hydrogen production from water. Herein, N-doped Ni3S2/N-doped MoS2 1D hetero-nanowires supported by Ni foam (N-Ni3S2/N-MoS2/NF) are readily synthesized through a chemical transformation strategy by using NiMoO4 nanowire array growth on Ni foam (NiMoO4/NF) as the starting material. With the in situ generation of Ni3S2/MoS2 heterointerfaces within nanowires and the incorporation of N− anions, an extraordinary hydrophilic nature with abundant, well-exposed active sites and optimal reaction dynamics for both oxidation and reduction of water are obtained. Attributed to these properties, as-converted N-Ni3S2/N-MoS2/NF exhibits highly efficient electrocatalytic activities for both hydrogen and oxygen evolution reactions under alkaline conditions. The superior bifunctional properties of N-Ni3S2/N-MoS2/NF enable it to effectively catalyze the overall water-splitting reaction. 相似文献
16.
Dr. Weixin Zou Lixia Xu Yu Pu Haojie Cai Xiaoqian Wei Yidan Luo Dr. Lulu Li Prof. Dr. Bin Gao Prof. Dr. Haiqin Wan Prof. Dr. Lin Dong 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(19):5058-5064
Bimetallic AgPd nanoparticles have been synthesized before, but the interfacial electronic effects of AgPd on the photocatalytic performance have been investigated less. In this work, the results of hydrogen evolution suggest that the bimetallic AgPd/g-C3N4 sample has superior activity to Ag/g-C3N4 and Pd/g-C3N4 photocatalysts. The UV/Vis diffuse reflectance spectroscopy, X-ray photoelectron spectroscopy, CO adsorption diffuse reflectance FTIR spectroscopy, and FTIR results demonstrate that in the AgPd/g-C3N4, the surface electronic structures of Pd and Ag are changed, which is beneficial for faster photogenerated electron transfer and greater H2O molecule adsorption. In situ ESR spectra suggest that, under visible light irradiation, there is more H2O dissociation to radical species on the AgPd/g-C3N4 photocatalyst. Furthermore, DFT calculations confirm the interfacial electronic effects of AgPd/g-C3N4, that is, Pdδ−⋅⋅⋅Agδ+, and the activation energy of H2O molecule dissociation on AgPd/g-C3N4 is the lowest, which is the main contributor to the enhanced photocatalytic H2 evolution. 相似文献
17.
Sergei V. Chapyshev Denis V. Korchagin Paulo Costa Wolfram Sander 《Magnetic resonance in chemistry : MRC》2022,60(8):829-835
The first X-band EPR spectrum containing only non-overlapping signals of septet pyridyl-2,4,6-trinitrene and triplet pyridylnitrenes is reported. This spectrum was recorded after photolysis of 2,4,6-triazidopyridine in solid argon at 5 K. The zero-field splitting (ZFS) parameters of this trinitrene as well as of intermediate triplet mononitrenes and quintet dinitrenes formed at early stages of the photolysis were determined using the combination of modern computer line-shape spectral simulations and density functional theory (DFT) calculations. It was found that septet pyridyl-2,4,6-trinitrene has the record negative parameter DS = −0.1031 cm−1 among all known to date septet pyridyl-2,4,6-trinitrenes and may be of interest as a model multi-qubit spin system for investigations of quantum computation processing. 相似文献
18.
This review discusses the latest advances in electrodeposition of nanostructured catalysts for electrochemical energy conversion: fuel cells, water splitting, and carbon dioxide electroreduction. The method excels at preparing efficient and durable nanostructured materials, such as nanoparticles, single atom clusters, hierarchical bifunctional combinations of hydroxides, selenides, phosphides, and so on. Yet, in most cases, chemical composition cannot be decoupled from catalyst morphology. This compromises the rational design of electrodeposition procedures because performance indicators depend on both morphology and surface chemistry. We expect electrodeposition will keep unraveling its potential as the preferred method for electrocatalyst synthesis once a deeper understanding of the electrochemical growth process is combined with complex chemistries to have control of the morphology and the surface composition of complex (bifunctional) electrocatalysts. 相似文献
19.
A non‐iterative implicit algorithm for the solution of advection–diffusion equation on a sphere 下载免费PDF全文
Yuri N. Skiba 《国际流体数值方法杂志》2015,78(5):257-282
A numerical algorithm for the solution of advection–diffusion equation on the surface of a sphere is suggested. The velocity field on a sphere is assumed to be known and non‐divergent. The discretization of advection–diffusion equation in space is carried out with the help of the finite volume method, and the Gauss theorem is applied to each grid cell. For the discretization in time, the symmetrized double‐cycle componentwise splitting method and the Crank–Nicolson scheme are used. The numerical scheme is of second order approximation in space and time, correctly describes the balance of mass of substance in the forced and dissipative discrete system and is unconditionally stable. In the absence of external forcing and dissipation, the total mass and L2‐norm of solution of discrete system is conserved in time. The one‐dimensional periodic problems arising at splitting in the longitudinal direction are solved with Sherman–Morrison's formula and Thomas's algorithm. The one‐dimensional problems arising at splitting in the latitudinal direction are solved by the bordering method that requires a prior determination of the solution at the poles. The resulting linear systems have tridiagonal matrices and are solved by Thomas's algorithm. The suggested method is direct (without iterations) and rapid in realization. It can also be applied to linear and nonlinear diffusion problems, some elliptic problems and adjoint advection–diffusion problems on a sphere. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
20.
《Comptes Rendus Mecanique》2014,342(10-11):583-594
In this paper we focus on WENO-based methods for the simulation of the 1D Quasi-Relativistic Vlasov–Maxwell (QRVM) model used to describe how a laser wave interacts with and heats a plasma by penetrating into it. We propose several non-oscillatory methods based on either Runge–Kutta (explicit) or Time-Splitting (implicit) time discretizations. We then show preliminary numerical experiments. 相似文献